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Synthesis of cis-hydrindan-2,4-diones bearing an all.carbon quaternary center by a Danheiser annulation

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A straightforward synthetic entry to functionalized hydrindane compounds based on a rapid assembly of the core nucleus by a Danheiser cycloaddition is reported. Valuable bicyclic building blocks containing the fused five and six-membered carbocyclic ring system can be achieved in only four steps from a simple acyclic β-keto ester. Keywords: alkaloid; Danheiser annulation; decahydroquinoline

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Beilstein Journal of Organic Chemistry, 2018, vol. 14, p. 2597-2601

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cc-by (c) Saborit Villarroya, Gisela et al., 2018

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

# metadata.dc.title[].value
Synthesis of cis-hydrindan-2,4-diones bearing an all.carbon quaternary center by a Danheiser annulation