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Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent

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A synthetic equivalent of the Nazarov reagent, the silyl derivative 2, able to undergo base-catalyzed double Michael addition reactions with a,b-unsaturated carbonyl compounds, has been developed. The new reagent satisfactorily reacts with unsaturated indolo[2,3-a]quinolizidine lactams to give pentacyclic yohimbinone-type derivatives.

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Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)

# metadata.dc.title[].value
Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent