# name
A new Method for determining Compound Specific Carbon Isotope of Chlorinated Solvents in Porewater

# metadata.dc.description.abstract[].value
A new method for the extraction of chlorinated solvents (CSs) from porewater with dimethylacetamide (DMA) used as a solvent and the determination of δ13C by gas chromatography-isotope ratio mass spectrometry (GC-IRMS) with solid-phase microextraction (SPME) are presented. This method was used for the determination of δ13C of chloroethenes and chloromethanes. The extraction of the CSs from porewater with DMA led to a minimal loss of mass of solvent and chlorinated compounds. The accuracy of the method was verified with the analysis of the pure injected compounds using elemental analyser - isotope ratio mass spectrometry (EA-IRMS). It has been effectively applied in a study area in saturated soil samples of a pollutant source zone of perchloroethylene (PCE) and trichloroethylene (TCE). The limit of quantification of the new method was 0.034 µg/g for PCE and TCE for 10-20 g of soil sample. This new method allows for compound-specific isotope analysis (CSIA) of CSs in porewater, which can be beneficial in sites where the identification of contamination sources and the behaviour of the contaminants are not clear.

# metadata.dc.relation.ispartof[].value
Groundwater Monitoring & Remediation, 2021

# metadata.dc.rights[].value
(c) National Ground Water Association, 2021

# metadata.dc.source[].value
Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

# metadata.dc.title[].value
A new Method for determining Compound Specific Carbon Isotope of Chlorinated Solvents in Porewater