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Stereoselective Acetate Aldol Reactions From Metal Enolates

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This review deals with metal enolate-mediated stereoselective acetate aldol reactions. It summarizes recent advances on aldol additions of unsubstituted metal enolates from chiral auxiliaries, stoichiometric and catalytic Lewis acids, or acting in substrate- controlled reactions, which provide stereocontrolled aldol transformations that allow the efficient synthesis of structurally complex natural products.

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Synthesis. Journal of Synthetic Organic Chemistry, 2011, vol. 2011, num. 14, p. 2175-2191

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Articles publicats en revistes (Química Inorgànica i Orgànica)

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Stereoselective Acetate Aldol Reactions From Metal Enolates