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Template arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridges

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Anovel {−Ni12Na2-Ni-}n chain has been characterized fromthe reaction between 2-pyridylcyanoxime, (pyC{CN}NOH), and nickel(II) sulfate. The template synthesis around a Na+ cation gives an unprecedented arrangement of four nickel triangles coordinated to the central sodium ion by sulfato bridges.

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Inorganic Chemistry Communications, 2014, vol. 43, p. 169-172

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Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

# metadata.dc.title[].value
Template arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridges