Gómez Palomino, AlejandroRomea, PedroUrpí Tubella, Fèlix2019-02-122019-07-012018-07-010039-7881https://hdl.handle.net/2445/128156A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates.6 p.application/pdfeng(c) Georg Thieme Verlag, 2018TitaniEstereoquímicaQuiralitatTitaniumStereochemistryChiralityinfo:eu-repo/semantics/article6811082019-02-12info:eu-repo/semantics/openAccess