Oyarzabal, I.Ruiz Dueñas, J.Ruiz Sabín, EliseoAravena Ponce, Daniel AlejandroSeco, J. M.Colacio, Enrique2020-03-312020-03-312015-06-171359-7345https://hdl.handle.net/2445/154553The trinuclear complex [ZnCl(l-L)Dy(l-L)ClZn]PF6 exhibits a single- molecule magnetic behaviour under zero field with a relatively large effective energy barrier of 186 cm1. Ab initio calculations reveal that the relaxation of the magnetization is symmetry-driven (the DyIII ion possesses a C2 symmetry) and occurs via the second excited state.4 p.application/pdfeng(c) Oyarzabal, I. et al., 2015MagnetismeIons metàl·licsMagnetismMetal ionsIncreasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited stateinfo:eu-repo/semantics/article6563572020-03-31info:eu-repo/semantics/openAccess