Costa Villén, ErnestoFont Bardia, Ma. MercedesMayans Ayats, JúliaEscuer Fité, Albert2025-07-312025-07-312024-07-031528-7483https://hdl.handle.net/2445/222730A family of discrete dinuclear complexes [MIILnIII] (M = Cu, Ni and Ln = Ce, Gd, Tb, Dy, Er, Yb) has been synthesized from the use of the compartmental Schiff base ligand H4L (3,3′-((1E,1′E)-(ethane-1,2-diylbis- (azaneylylidene)) bis(methaneylylidene))bis(benzene-1,2-diol)), obtained from the condensation of ethylenediamine and 2,3-dihydroxybenzaldehyde. All of the complexes have been structurally and magnetically characterized. The dynamic magnetic measurements show that the [CuIILnIII] and [NiIILnIII] derivatives exhibit ac response as a function of the d-cation. Noteworthily, the isotropic GdIII complexes exhibit a slow relaxation of magnetization.12 p.application/pdfengcc-by (c) Costa Villén, Ernesto, et al., 2024http://creativecommons.org/licenses/by/3.0/es/LantaniPropietats magnètiquesLligandsLanthanumMagnetic propertiesLigandsinfo:eu-repo/semantics/article7515212025-07-31info:eu-repo/semantics/openAccess