Casellas, Nicolas M.Pujals Riatós, SilviaBochicchio, DavidePavan, Giovanni M.Torres, TomásAlbertazzi, LorenzoGarcía Iglesias, Miguel2019-01-172019-03-272018-03-27https://hdl.handle.net/2445/127393Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).4 p.application/pdfeng(c) Casellas et al., 2018PolimeritzacióEstructura molecularAiguaPolymerizationMolecular structureWaterFrom isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer designinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccess