Kennington, Stuart C. D.Gómez Palomino, AlejandroSalomó i Prat, ErnestRomea, PedroUrpí Tubella, FèlixFont Bardia, Ma. Mercedes2019-02-062019-06-142018-06-141477-0520https://hdl.handle.net/2445/127958A comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation10 p.application/pdfeng(c) Kennington, Stuart C. D. et al., 2018TitaniEstereoquímicaTitaniumStereochemistryGeneral and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliaryinfo:eu-repo/semantics/article6811382019-02-06info:eu-repo/semantics/openAccess29915837