Pinto Martínez, AndreaSpigolon, G.Gavara, RaquelZonta, C.Licini, G.Rodríguez Raurell, Laura2020-12-172021-07-212020-07-211477-9226https://hdl.handle.net/2445/172836Three gold(I) tripodal complexes containing the tris(2-pyridylmethyl)amine (TPA) ligand coordinated to Au-PR3 moieties (PR3 = 1,3,5-triaza-7-phosphatricyclo[3.3.1.13.7]decane, PTA (1), 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, DAPTA (2) and triphenylphosphane (3)) were prepared together with a cage-like structure containing triphosphane 1,1,1-tris(diphenylphosphinomethyl)ethane (4). The luminescence of these complexes has been studied and they show a red shift upon the formation of heterometallic complexes by reaction with Zn(NO3)2, CuCl and [Cu(CH3CN)4]BF4. The different coordination motifs of the Zn2+ and Cu+ heterometallic species and the resulting changes in the recorded absorption, emission and NMR spectra were analysed and supported by TD-DFT calculations.13 p.application/pdfeng(c) Pinto, Andrea et al., 2020OrLuminescènciaOptoelectrònicaGoldLuminescenceOptoelectronicsinfo:eu-repo/semantics/article7053512020-12-17info:eu-repo/semantics/openAccess