Reductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2−Csp3 Bonds and Subsequent Competition between Csp2−H and Csp3−H Bond Activation

Crespo Vicente, Margarita Ma.Anderson, Craig M.Kfoury, NicoleFont Bardia, Ma. MercedesCalvet Pallàs, Maria Teresa2024-05-072024-05-0720120276-7333https://hdl.handle.net/2445/210984<p>Reductive elimination reactions of the cyclometalated platinum(IV) compounds [PtMe2Br{C6H4CH NCH2(4-ClC6H4)}L] (L = SMe2, PPh3) to form Csp3−Csp2 bonds, followed by either exclusive Csp2−H bond activation (L = SMe2) or competition between Csp2−H and Csp3−H bond activation (L = PPh3) are reported. Reductive elimination to form a C−Br bond is also reported.</p>17 p.application/pdfeng(c) American Chemical Society, 2012LligandsHidrocarbursLigandsHydrocarbonsReductive Elimination from Cyclometalated Platinum(IV) Complexes To Form Csp2−Csp3 Bonds and Subsequent Competition between Csp2−H and Csp3−H Bond Activationinfo:eu-repo/semantics/article6208812024-05-07info:eu-repo/semantics/openAccess