Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent

Amat Tusón, MercedesArioli, FedericaPérez Bosch, MariaMolins i Grau, EliesBosch Cartes, Joan2017-03-082017-03-082013-04-251523-7060https://hdl.handle.net/2445/108108A synthetic equivalent of the Nazarov reagent, the silyl derivative 2, able to undergo base-catalyzed double Michael addition reactions with a,b-unsaturated carbonyl compounds, has been developed. The new reagent satisfactorily reacts with unsaturated indolo[2,3-a]quinolizidine lactams to give pentacyclic yohimbinone-type derivatives.4 p.application/pdfeng(c) American Chemical Society , 2013Indicadors (Química)Proves i reactius químicsLactamesIndicators and test-papersChemical tests and reagentsLactamsPreparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagentinfo:eu-repo/semantics/article6240642017-03-08info:eu-repo/semantics/openAccess