Alcázar, LauraFont Bardia, Ma. MercedesEscuer Fité, Albert2020-06-062020-06-0620151434-1948https://hdl.handle.net/2445/164598A new Mn16 topology consisting of one hexanuclear {MnII2MnIII4} unit coordinated inside a decametallic {MnII6MnIII2MnIV 2} wheel was synthesized from 2-pyridyl-cyanoxime and azido ligands. A new tetrazole-2-pyridylketoneoximate ligand was obtained in situ by cyclization of the cyano group and azide mediated by manganese cations.15 p.application/pdfeng(c) Wiley-VCH, 2015ManganèsPropietats magnètiquesManganeseMagnetic propertiesA Mn6 cluster inside a Mn10 wheel: characterization of a Mn16-oximate complex and the new tetrazole-2-pyridilketoneokimate ligandinfo:eu-repo/semantics/article6496212020-06-06info:eu-repo/semantics/openAccess