Bis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvate

Esquius, G.Pons, JosefinaYáñez, R.Ros, JosepSolans, Xavier, 1949-2007Font Bardia, Ma. Mercedes2020-05-142020-05-1420020108-2701https://hdl.handle.net/2445/160142In the title compound, [Rh2(C8H15N3)2(C8H12)2]Cl2·CH2Cl2·CH3OH, the dinuclear RhI complex has C2 symmetry and the two pyrazolato ligands act as [mu]-bridges. The coordination of each RhI cation is completed by one cyclooctadiene (COD) ligand. It is shown that the average Rh-C(COD) distance is linearly dependent on the Rh-N(pyrazole) distance in this type of compound, and this is ascribed to the steric hindrance produced by the packing.2 p.application/pdfeng(c) International Union of Crystallography, 2002Cristal·lografiaCrystallographyBis[μ-4-(ethylammoniomethyl)-3,5-dimethylpyrazolato-kappa N-2(1): N-2]bis[(η 4- 1,5-cyclooctadiene)rhodium(I)] dichloride dichloromethane methanol solvateinfo:eu-repo/semantics/article5631472020-05-14info:eu-repo/semantics/openAccess