Lupu, MariusZaulet, AdnanaTeixidor, FrancescRuiz Sabín, EliseoViñas, Clara2020-05-122020-05-122015-04-270947-6539https://hdl.handle.net/2445/159723It was possible to synthesize and isolate redox couples in which both partners are negatively charged. The handy framework is [3,3'-Co(1,2-closo-C2B9H11)2]-. The E½ potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3'-Co(1,2-closo-C2B9H7I4)2]- is the most favorable as it is isolatable and stable in air.10 p.application/pdfeng(c) Wiley-VCH, 2015CobaltReacció d'oxidació-reduccióCobaltOxidation-reduction reactionNegatively charged metallacarborane redox couples with both members stable to airinfo:eu-repo/semantics/article6532022020-05-12info:eu-repo/semantics/openAccess