A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response

Vicente Castillo, RamónEl Fallah El Boufrahi, Mohamed SalahCasanovas Bayo, BertaFont Bardia, Ma. MercedesEscuer Fité, Albert2020-05-142020-05-142016-06-200020-1669https://hdl.handle.net/2445/160321One new MnII 2MnIII 6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII 3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.10 p.application/pdfeng(c) American Chemical Society , 2016GeoquímicaMagnetismeEstructura cristal·lina (Sòlids)GeochemistryMagnetismLayer structure (Solids)A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Responseinfo:eu-repo/semantics/article6628222020-05-14info:eu-repo/semantics/openAccess