Stereoselective and catalytic synthesis of anti-β-Alkoxy-α-azido carboxylic derivatives

Fernandez-Valparis, JavierRomea, PedroUrpí Tubella, FèlixFont Bardia, Ma. Mercedes2019-02-132019-02-132017-12-011523-7060https://hdl.handle.net/2445/128219Direct addition of a chiral N-azidoacetyl thiazolidinethione to a variety of dialkyl acetals catalyzed by a commercially available and structurally simple nickel(II) complex gives access in good yields and a highly stereocontrolled manner to anti-beta-alkoxy-alpha-azido carboxylic derivatives which, in turn, can be easily converted into a wide array of enantiomerically pure compounds.4 p.application/pdfeng(c) American Chemical Society , 2017CatàlisiSíntesi orgànicaCatalysisOrganic synthesisStereoselective and catalytic synthesis of anti-β-Alkoxy-α-azido carboxylic derivativesinfo:eu-repo/semantics/article6751932019-02-13info:eu-repo/semantics/openAccess29160074