Casanovas Bayo, BertaZinna, FrancescoDi Bari, LorenzoEl Fallah El Boufrahi, Mohamed SalahFont Bardia, Ma. MercedesVicente Castillo, Ramón2020-05-312020-05-312017-05-211477-9226https://hdl.handle.net/2445/163379The reaction of Ln(NO3)(2)center dot 6H(2)O (Ln = Tb and Eu) with (S)-(+)-2-phenylpropionic acid (S-HL) and 1,10-phenanthroline (phen) in EtOH/H2O allows the isolation of the dinuclear chiral compounds of the formula [Ln(2)(S-L)(6)(phen)(2)]center dot 2.5 center dot S-HL in which Ln = Tb (S-1), Ln = Eu (S-2). The same synthesis by using (R)-(-)-2-phenylpropionic acid (R-HL) instead of (S)-(+)-2-phenylpropionic acid allows the isolation of the enantiomeric compounds with the formula [Ln(2)(R-L)(6)(phen)(2)]center dot 2 center dot 5 center dot R-HL where Ln = Tb (R-1), Ln = Eu (R-2). All compounds show sensitized luminescence. The luminescence study, including the circularly polarized luminescence spectra of the four compounds, is reported. The magnetic behavior of S-1 and S-2 is also reported.32 p.application/pdfeng(c) Casanovas Bayo, Berta et al., 2017Estructura cristal·lina (Sòlids)LuminescènciaLayer structure (Solids)Luminescenceinfo:eu-repo/semantics/article6803722020-05-31info:eu-repo/semantics/openAccess