Homs Martí, NarcísCordoba Sola, AlbertoMartínez-Alanis, Paulina R.Alcobé i Ollé, XavierGüell Vilà, FrankRamírez de la Piscina, Pilar2024-02-152024-02-152023-110360-3199https://hdl.handle.net/2445/207642ZnO nanowires (NWs) with wurzite structure and a very high [0001] preferred orientation were grown on a ZnO thin film, from a gas-solid process, in the absence of catalyst. ZnO NWs were characterized by FESEM, XRD, HRTEM, XPS, PL and Raman spectroscopy and used as photocatalysts for the photo-transformation of ethanol(aq) in the gas phase. The existence of different defects such as oxygen vacancies was evidenced. The photocatalytic process was followed by in-situ diffuse reflectance infrared spectroscopy (DRIFTS) coupled to on-line mass spectrometry (MS) analysis. The surface species determined during the irradiation (λ = 365 nm) of ZnO NWs under ethanol/water vapor flow at room temperature are related with the hydrogen production and carbon-containing products evolved.7 p.application/pdfengcc-by-nc-nd (c) Elsevier Ltd, 2023http://creativecommons.org/licenses/by-nc-nd/4.0/FotocatàlisiMetanolEspectroscòpia RamanPhotocatalysisMethanolRaman spectroscopyH2 generation from aqueous ethanol over ZnO nanowires, the photo-transformation of surface speciesinfo:eu-repo/semantics/article7414462024-02-15info:eu-repo/semantics/openAccess