Agarwal, Rashmi A.Mukherjee, SoumyaSañudo Zotes, Eva CarolinaGhosh, Sujit KBharadwaj, Parimal K2020-03-272020-03-272014-10-211528-7483https://hdl.handle.net/2445/154179A porous coordination polymer {[Mn2(DBIBA)3]×(NO3)·3DMF·4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. This compound shows significant selective CO2 uptake at low temperature. 1 exhibits antiferromagnetic properties below 17 K, confirmed by magnetic susceptibility measurements. Four new coordination polymers: {[Mn2(DBIBA)3]·ClO4·3DMF·3H2O}n (2), {[Mn2(DBIBA)3]×Cl×DMF×H2O}n (3), {[Mn2(DBIBA)3]×NO3×CH3OH×7H2O}n (4) and {[Mn2(DBIBA)3]×NO3×2CH3COCH3×H2O}n (5), have been synthesized from 1 via anion/solvent exchange protocols at room temperature.8 p.application/pdfeng(c) American Chemical Society , 2014LligandsQuímica organometàl·licaLigandsOrganometallic chemistryinfo:eu-repo/semantics/article6550772020-03-27info:eu-repo/semantics/openAccess