Efthymiou, Constantinos G.Fhuaráin, Áine NíMayans Ayats, JúliaTasiopoulos, AnastasiosPerlepes, Spyros P.Papatriantafyllopoulou, Constantina2019-07-162019-07-162019-06-042312-7481https://hdl.handle.net/2445/137298The synthesis, structural characterization and magnetic study of novel CoII/4f and CoII/YIII clusters are described. In particular, the initial employment of di-2-pyridyl ketone, (py)2CO, in mixed metal Co/4f chemistry, provided access to four triangular clusters, [CoII2MIII{(py)2C(OEt)(O)}4(NO3)(H2O)]2[M(NO3)5](ClO4)2 (M = Gd, 1; Dy, 2; Tb, 3; Y, 4), where (py)2C(OEt)(O)− is the monoanion of the hemiketal form of (py)2CO. Clusters 1-4 are the first reported Co/4f (1-3) and Co/Y (4) species bearing (py)2CO or its derivatives, despite the fact that over 200 metal clusters bearing this ligand have been reported so far. Variable-temperature, solid-state dc and ac magnetic susceptibility studies were carried out on 1-4 and revealed the presence of weak ferromagnetic exchange interactions between the metal ions (JCo-Co = +1.3 and +0.40 cm−1 in 1 and 4, respectively; JCo-Gd = +0.09 cm−1 in 1). The ac susceptibility studies on 2 revealed nonzero, weak out-of-phase (χ''M) signals below ~5 K.12 p.application/pdfengcc-by (c) Efthymiou, Constantinos G. et al., 2019http://creativecommons.org/licenses/by/3.0/esCobaltMagnetismeClústers metàl·licsMetalls de terres raresCobaltMagnetismMetal clustersRare earth metalsinfo:eu-repo/semantics/article6906462019-07-16info:eu-repo/semantics/openAccess