Diego, RosaDarawsheh, Mohanad D.Barrios Moreno, Leoní AlejandraSadurní, AnnaGarcia-Anton, JordiLloyd-Williams, PaulTeat, Simon J.Roubeau, OlivierAguilà Avilés, DavidAromí Bedmar, Guillem2020-03-272020-11-232019-11-231477-9226https://hdl.handle.net/2445/154185A new bis-(β-diketone) ligand featuring built-up structural asymmetry yields non-symmetric Fe(iii) and Ga(iii) dinuclear, triple-stranded helicates by design. Their structural properties have been studied, both in solid state and in solution, and compared with their corresponding symmetric analogues. The robustness observed shows the potential of this synthetic strategy to develop non-symmetric helicoidal motifs with specific functional groups. © 2019 The Royal Society of Chemistry.4 p.application/pdfeng(c) Diego, Rosa et al., 2019LligandsCoureDifracció de raigs XLigandsCopperX-rays diffractioninfo:eu-repo/semantics/article6937522020-03-27info:eu-repo/semantics/openAccess