Duran, JordiRodríguez, PaulaVermeer, WardCompanyó Montaner, Xavier2025-07-312025-07-312024-10-041523-7060https://hdl.handle.net/2445/222731Herein we describe the organocatalytic asymmetric allylic benzylborylation of allyl fluorides with α-silyl benzylboronic esters. The catalytic protocol leverages the singular features of fluoride as an unconventional leaving group, enabling the catalytic generation of reactive α-boryl carbanion species through desilylative activation. It allows the construction of a wide set of homoallylic benzylated organoboronates bearing two contiguous stereocenters. The chiral boronate installed in the products serves as a synthetic lynchpin to construct complex chemical architectures in a stereospecific manner.6 p.application/pdfengcc-by (c) Duran, Jordi et al., 2024http://creativecommons.org/licenses/by/3.0/es/Compostos orgànicsAnionsEstructura molecularOrganic compoundsAnionsMolecular structureinfo:eu-repo/semantics/article7516842025-07-31info:eu-repo/semantics/openAccess