Pilichos, EvangelosTubau Ribot, ÀnniaSpeed Castro, SaskiaFont Bardia, Ma. MercedesEscuer Fité, AlbertGrabulosa, ArnaldMayans Ayats, Júlia2024-12-122024-12-122023-01-251477-9226https://hdl.handle.net/2445/217061A new family of lanthanide compounds has been synthesized using 1,2-bis(diphenylphosphino)ethane dioxide (dppeO2) as an O-donor ligand through the phosphoryl group to lanthanide(III) cations and structurally, magnetically and optically studied. Depending on the lanthanide, two different topologies appear: the two-dimensional structure [LnIII(dppeO2)1.5(NO3)3(H2O)0.5]n (Ln = Ce (1), Sm (2) and Dy (6)) and the one-dimensional structure [Ln(dppeO2)(NO3)3DMF]n (Ln = Eu (3), Gd (4) and Tb (5)). Some of the Ln-derived complexes have been used as structural probes, while others have been synthesized to use the specific characteristics of each cation to take advantage of their magnetic/luminescence properties. Complex 6 presents slow relaxation of the magnetization while 2, 3 and 5 present emitting properties in the visible range.10 p.application/pdfengcc-by (c) Pilichos, Evangelos et al., 2023http://creativecommons.org/licenses/by/3.0/es/Radiocristal·lografiaPropietats magnètiquesÒpticaX-ray crystallographyMagnetic propertiesOpticsinfo:eu-repo/semantics/article7367952024-12-12info:eu-repo/semantics/openAccess