Template arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridges

Esteban Jarne, JordiFont Bardia, Ma. MercedesEscuer Fité, Albert2020-06-122020-06-122014-051387-7003https://hdl.handle.net/2445/165281Anovel {−Ni12Na2-Ni-}n chain has been characterized fromthe reaction between 2-pyridylcyanoxime, (pyC{CN}NOH), and nickel(II) sulfate. The template synthesis around a Na+ cation gives an unprecedented arrangement of four nickel triangles coordinated to the central sodium ion by sulfato bridges.13 p.application/pdfeng(c) Elsevier B.V., 2014Química supramolecularPropietats magnètiquesSulfat de ferroSupramolecular chemistryMagnetic propertiesFerrous sulfateTemplate arrangement of {Ni3(&m3-OH)(SO4)(R-NO)2}+ fragments around Na+ cations: An unprecedented {Ni12Na} unit linked by oximate and sulfate bridgesinfo:eu-repo/semantics/article6348902020-06-12info:eu-repo/semantics/openAccess