Esteban Jarne, JordiFont Bardia, Ma. MercedesSánchez Costa, JoséTeat, Simon J.Escuer Fité, Albert2020-06-122020-06-1220140020-1669https://hdl.handle.net/2445/165286In the present work, five new Ni5 clusters employing the versatile 2-pyridylcyanoxime ligand have been synthesized and chemically, structurally, and magnetically characterized. The crystallographic examination of these Ni5 clusters together with those already published in the literature, giving a total number of 14 complexes, exhibiting up to 8 different topologies for which the relationship between topology, reaction conditions and magnetic response has been analyzed. DC magnetic measurements were carried in the 300-2 K range for the new complexes and the analysis of the experimental data revealed an antiferromagnetic response for the oximato mediated interactions with a variety of ground states (S = 0, 1, 3) as function of the cluster topology.36 p.application/pdfeng(c) American Chemical Society , 2014LligandsPropietats magnètiquesTeoria quànticaLigandsMagnetic propertiesQuantum theoryinfo:eu-repo/semantics/article6348892020-06-12info:eu-repo/semantics/openAccess