Santos, DavidAriza Piquer, XavierGarcía Gómez, JordiLloyd-Williams, PaulMartínez Laporta, AgustínSánchez Zarzalejo, Carolina2013-05-212014-12-3120130022-3263https://hdl.handle.net/2445/43586An enantioselective approach to (-)-isoavenaciolide was achieved starting from 1- undecyn-3-ol. The synthesis relied upon the preparation of a chiral 4-silyloxy-2-alkenylborane by hydroboration of a protected 2,3-allenol and subsequent stereoselective addition to 2- thiophenecarboxaldehyde6 p.application/pdfeng(c) American Chemical Society , 2013BiomolèculesProductes naturalsSíntesi asimètricaMedicaments antibacteriansFungicidesBiomoleculesNatural productsAsymmetric synthesisAntibacterial agentsFungicidesinfo:eu-repo/semantics/article6197372013-05-17info:eu-repo/semantics/openAccess23339655