Casanovas Bayo, BertaSpeed, SaskiaEl Fallah El Boufrahi, Mohamed SalahVicente Castillo, RamónFont Bardia, Ma. MercedesZinna, FrancescoDi Bari, Lorenzo2020-05-182020-05-182019-01-101477-9226https://hdl.handle.net/2445/160862The reaction of LnCl3·6H2O with (S)-(+)-2-(6-methoxy-2-naphthyl)propionic acid (S-HL), best known as naproxen, and 1,10-phenanthroline (phen) in EtOH allows the isolation of dinuclear chiral compounds S-1-4 of the formula [Ln2(S-L)6(phen)2]·3DMF·H2O [Ln(III) = Eu (1), Gd (2), Tb (3) and Dy (4)]. The use of the R-enantiomeric species of the HL ligand led to complexes R-1-4 with the formula [Ln2(R-L)6(phen)2]·3DMF·H2O. Compounds R- and S-1, 3 and 4 show strong sensitized metal-centred luminescence in the visible region. Moreover, Dy(III) complexes R- and S-4 display field-induced singlemolecule magnet (SMM) behaviour. For chiral and emissive compounds circularly polarized luminescence (CPL) measurements have also been performed.27 p.application/pdfeng(c) Casanovas Bayo, Berta et al., 2019Estructura cristal·lina (Sòlids)MagnetismeLayer structure (Solids)Magnetisminfo:eu-repo/semantics/article6842722020-05-18info:eu-repo/semantics/openAccess