Orgué Gassol, SílviaFlores-Gaspar, AreliBiosca, MariaPàmies, OscarDiéguez, MontserratRiera i Escalé, AntoniVerdaguer i Espaulella, Xavier2015-12-042015-10-021359-7345https://hdl.handle.net/2445/68334The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.4 p.application/pdfengcc by (c) Orgué Gassol, Sílvia et al., 2015http://creativecommons.org/licenses/by/3.0/es/HidròlisiLligandsCatàlisi asimètricaCompostos de borHydrolysisLigandsEnantioselective catalysisBoron compoundsinfo:eu-repo/semantics/article6545782015-12-04info:eu-repo/semantics/openAccess26477668