Versatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditions

Corominas, Albert (Corominas Tarruella)Montaña Pedrero, Ángel-Manuel2013-09-172014-12-3120130039-7911https://hdl.handle.net/2445/46043A method to generate carbonylic compounds from alkynes under mild and neutral conditions, with excellent functional group compatibility and high yields, is described. Hydration takes place under catalytic conditions by using from 0.1 to 0.2 equivalents of the easily available and inexpensive mercury(II) p-toluensulfonamidate in a hydroalcoholic solution. After use the catalyst is iner tized and/or recycled ...24 p.application/pdfeng(c) Taylor and Francis, 2013Compostos carbonílicsQuímica orgànicaCarbonyl compoundsOrganic chemistryVersatile methodology to hydrate alkynes, in the presence of a wide variety of functional groups, with Mercury(II) p-Toluensulfonamidate, under catalytic, mild and neutral conditionsinfo:eu-repo/semantics/article6239382013-09-17info:eu-repo/semantics/openAccess