Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of nanogel vectors

Galia, AlessandroLanzalaco, SoniaSabatino, Maria AntoniettaDispenza, CleliaScialdone, OnofrioSirés Sadornil, Ignacio2020-06-092020-06-092016-12-101388-2481https://hdl.handle.net/2445/164861A facile electrosynthesis route for the preparation of polymer nanogels based on the in situ production of hydroxyl radicals is reported for the first time. Electro-Fenton process with continuous H2O2 electrogeneration and Fe2+ regeneration performs better than electro-oxidation with a boron-doped diamond or dimensionally stable anode for promoting crosslinking of poly(vinylpyrrolidone).5 p.application/pdfengcc-by-nc-nd (c) Elsevier B.V., 2016http://creativecommons.org/licenses/by-nc-nd/3.0/esOxidació electroquímicaPolímersRadicals (Química)Electrolytic oxidationPolymersRadicals (Chemistry)Crosslinking of poly(vinylpyrrolidone) activated by electrogenerated hydroxyl radicals: a first step towards a simple and cheap synthetic route of nanogel vectorsinfo:eu-repo/semantics/article6564172020-06-09info:eu-repo/semantics/openAccess