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Title: Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent
Author: Amat Tusón, Mercedes
Arioli, Federica
Pérez Bosch, Maria
Molins i Grau, Elies
Bosch Cartes, Joan
Keywords: Indicadors (Química)
Proves i reactius químics
Indicators and test-papers
Chemical tests and reagents
Issue Date: 25-Apr-2013
Publisher: American Chemical Society
Abstract: A synthetic equivalent of the Nazarov reagent, the silyl derivative 2, able to undergo base-catalyzed double Michael addition reactions with a,b-unsaturated carbonyl compounds, has been developed. The new reagent satisfactorily reacts with unsaturated indolo[2,3-a]quinolizidine lactams to give pentacyclic yohimbinone-type derivatives.
Note: Versió postprint del document publicat a:
It is part of: Organic Letters, 2013, vol. 15, num. 10, p. 2470-2473
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ISSN: 1523-7060
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)

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