Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines

Flores-Gaspar, Areli; Orgué Gassol, Sílvia; Grabulosa, Arnald; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier

Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/108386

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DC Field	Value	Language
dc.contributor.author	Flores-Gaspar, Areli	-
dc.contributor.author	Orgué Gassol, Sílvia	-
dc.contributor.author	Grabulosa, Arnald	-
dc.contributor.author	Riera i Escalé, Antoni	-
dc.contributor.author	Verdaguer i Espaulella, Xavier	-
dc.date.accessioned	2017-03-14T08:59:50Z	-
dc.date.available	2017-03-14T08:59:50Z	-
dc.date.issued	2014-12-22	-
dc.identifier.issn	1359-7345	-
dc.identifier.uri	http://hdl.handle.net/2445/108386	-
dc.description.abstract	In non-coordinating solvents, borane was shown to be an efficient directing group for the stereoselective 1,2-addition of organolithium reagents to P-stereogenic N-phosphanylimines. Selectivity was reversed in coordinating solvents. This process can lead to novel ligand scaffolds for asymmetric catalysis.	-
dc.format.extent	4 p.	-
dc.format.mimetype	application/pdf	-
dc.language.iso	eng	-
dc.publisher	Royal Society of Chemistry	-
dc.relation.isformatof	Versió postprint del document publicat a: https://doi.org/10.1039/c4cc09106j	-
dc.relation.ispartof	Chemical Communications, 2014, vol. 51, p. 1941-1944	-
dc.relation.uri	https://doi.org/10.1039/c4cc09106j	-
dc.rights	(c) Flores-Gaspar, Areli et al., 2014	-
dc.source	Articles publicats en revistes (Química Inorgànica i Orgànica)	-
dc.subject.classification	Compostos organometàl·lics	-
dc.subject.classification	Lligands (Bioquímica)	-
dc.subject.classification	Catàlisi asimètrica	-
dc.subject.other	Organometallic compounds	-
dc.subject.other	Ligands (Biochemistry)	-
dc.subject.other	Enantioselective catalysis	-
dc.title	Borane as an efficient directing group. Stereoselective 1,2-addition of organometallic reagents to borane P-stereogenic N-phosphanylimines	eng
dc.type	info:eu-repo/semantics/article	-
dc.type	info:eu-repo/semantics/acceptedVersion	-
dc.identifier.idgrec	646126	-
dc.date.updated	2017-03-14T08:59:50Z	-
dc.rights.accessRights	info:eu-repo/semantics/openAccess	-
Appears in Collections:	Articles publicats en revistes (Química Inorgànica i Orgànica)

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