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http://hdl.handle.net/2445/128156| Title: | Stereoselective oxidation of titanium(IV) enolates with oxygen |
| Author: | Gómez Palomino, Alejandro Romea, Pedro Urpí Tubella, Fèlix |
| Keywords: | Titani Estereoquímica Quiralitat Titanium Stereochemistry Chirality |
| Issue Date: | 1-Jul-2018 |
| Publisher: | Georg Thieme Verlag |
| Abstract: | A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966 |
| It is part of: | Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726 |
| URI: | http://hdl.handle.net/2445/128156 |
| Related resource: | https://doi.org/10.1055/s-0037-1609966 |
| ISSN: | 0039-7881 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 681108.pdf | 437.41 kB | Adobe PDF | View/Open |
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