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Title: Stereoselective oxidation of titanium(IV) enolates with oxygen
Author: Gómez Palomino, Alejandro
Romea, Pedro
Urpí Tubella, Fèlix
Keywords: Titani
Issue Date: 1-Jul-2018
Publisher: Georg Thieme Verlag
Abstract: A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates.
Note: Versió postprint del document publicat a:
It is part of: Synthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726
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ISSN: 0039-7881
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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