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Title: | Enantioselective synthesis of indole alkaloids from chiral lactams |
Author: | Amat Tusón, Mercedes Pérez Bosch, Maria Bosch Cartes, Joan |
Keywords: | Alcaloides Lactames Síntesi orgànica Enantiòmers Alkaloids Lactams Organic synthesis Enantiomers |
Issue Date: | 2011 |
Publisher: | Georg Thieme Verlag |
Abstract: | This account reports on the use of (R)- or (S)-phenylglycinol- and (S)-tryptophanol-derived oxazolopiperidone lactams as building blocks for the enantioselective synthesis of structurally diverse indole alkaloids. 1 Introduction 2 Monoterpenoid Indole Alkaloids from (R)- or (S)-Phenylglycinol-Derived Lactams 2.1 Substituted Piperidines as Precursors for the Enantioselective Synthesis of Indole Alkaloids 2.1.1 (+)-Decarbomethoxytetrahydrosecodine 2.1.2 Enantiopure cis- and trans-(3-Ethylpiperidin-4-yl)acetates as Precursors for the Synthesis of Indolo- and Benzo-[a]quinolizidine Alkaloids 2.1.3 Indole Alkaloids Related to Cleavamine and Quebrach-amine 2.2 Uleine and Strychnos Alkaloids 2.3 The Ervatamine-Silicine Group 3 Indolo[2,3-a]quinolizidines from (S)-Tryptophanol-Derived Lactams 3.1 Indolo[2,3-a]quinolizidines and Analogues by Intramolecular Amidoalkylation Reactions: Synthesis of (R)-(+)-Deplancheine and (R)-(+)-Harmicine 3.2 Indolo[2,3-a]quinolizidines by a Modified Bischler-Napieralski Reaction: Formal Synthesis of (+)-Dihydrocorynantheine and (-)-Dihydrocorynantheol 4 Conclusion |
Note: | Versió postprint del document publicat a: https://doi.org/10.1055/s-0030-1259297 |
It is part of: | Synlett, 2011, vol. 2011, num. 2, p. 143-160 |
URI: | http://hdl.handle.net/2445/164346 |
Related resource: | https://doi.org/10.1055/s-0030-1259297 |
ISSN: | 0936-5214 |
Appears in Collections: | Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia) Articles publicats en revistes (Institut de Biomedicina (IBUB)) Articles publicats en revistes (Farmàcia, Tecnologia Farmacèutica i Fisicoquímica) |
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