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http://hdl.handle.net/2445/164364Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Soldevila-Sanmartín, Joan | - |
| dc.contributor.author | Ayllón, J. A. | - |
| dc.contributor.author | Calvet Pallàs, Maria Teresa | - |
| dc.contributor.author | Font Bardia, Ma. Mercedes | - |
| dc.contributor.author | Domingo, C. | - |
| dc.contributor.author | Pons, Josefina | - |
| dc.date.accessioned | 2020-06-04T19:45:50Z | - |
| dc.date.available | 2020-06-04T19:45:50Z | - |
| dc.date.issued | 2016-09 | - |
| dc.identifier.issn | 1387-7003 | - |
| dc.identifier.uri | http://hdl.handle.net/2445/164364 | - |
| dc.description.abstract | The synthesis and characterization of a mixed carboxylate paddle-wheel copper complex, with formula [Cu(μ- Pip)(μ-MeCO2)(MeOH)]2 (Pip = piperonylate or 1,3-benzodioxole-5-carboxylate and MeCO2 = acetate), is here reported. The described compound is a binuclear complex, each pair of similar carboxylate ligands occupyingmutually trans bridging positions,while the methanol occupies the apical positions. The dimers are arranged into 2D layers in the bc plane through a network of O-H⋯O hydrogen bonds established between themethanol and the acetate ligand. Magnetic studies showed a strong antiferromagnetic Cu⋯Cu interaction (J = −308 cm−1), in agreement with the presence of four μ-κO-κO′ carboxylates bridging the metallic centers in the binuclear complex. | - |
| dc.format.extent | 16 p. | - |
| dc.format.mimetype | application/pdf | - |
| dc.language.iso | eng | - |
| dc.publisher | Elsevier B.V. | - |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1016/j.inoche.2016.07.009 | - |
| dc.relation.ispartof | Inorganic Chemistry Communications, 2016, vol. 71, p. 90-93 | - |
| dc.relation.uri | https://doi.org/10.1016/j.inoche.2016.07.009 | - |
| dc.rights | cc-by-nc-nd (c) Elsevier B.V., 2016 | - |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es | - |
| dc.source | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | - |
| dc.subject.classification | Estructura cristal·lina (Sòlids) | - |
| dc.subject.classification | Coure | - |
| dc.subject.other | Layer structure (Solids) | - |
| dc.subject.other | Copper | - |
| dc.title | Synthesis, crystal structure and magnetic properties of a Cu(II) paddle-wheel complex with mixed bridges | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/acceptedVersion | - |
| dc.identifier.idgrec | 668103 | - |
| dc.date.updated | 2020-06-04T19:45:50Z | - |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
| Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) | |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 668103.pdf | 969 kB | Adobe PDF | View/Open |
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