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Title: Dimerization of highly pyramidalized 3,4,8,9-tetramethyltetracyclo[,9.04,8]dec-1(6)-ene to a hydrocarbon featuring four cyclohexane rings in boat conformation
Author: Rey Carrizo, Matías
Barniol-Xicota, Marta
Font Bardia, Ma. Mercedes
Vázquez Cruz, Santiago
Keywords: Compostos policíclics
Polycyclic compounds
Issue Date: 26-May-2014
Publisher: Wiley-VCH
Abstract: The synthesis, chemical trapping, and dimerization of a highly pyramidalized alkene is reported. Its dimer is a unique nonacycle featuring three planar cyclobutane rings, four cyclopentane rings, and four cyclohexane rings in boat conformations. The X-ray diffraction analysis showed a H-H distance between the flagpole hydrogen atoms of 1.999 and a separation of 2.619 between the two flagpole carbon atoms. The three cyclobutane rings of the dimer were thermally stable
Note: Versió postprint del document publicat a:
It is part of: Angewandte Chemie-International Edition, 2014, vol. 53, num. 31, p. 8195-8199
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ISSN: 1433-7851
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)

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