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http://hdl.handle.net/2445/179153
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DC Field | Value | Language |
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dc.contributor.author | Fernandez-Bartolomé, Estefania | - |
dc.contributor.author | Gamonal, Arturo | - |
dc.contributor.author | Santos, José | - |
dc.contributor.author | Khodabakhshi, Saeed | - |
dc.contributor.author | Rodríguez Sánchez, Eider | - |
dc.contributor.author | Sañudo Zotes, Eva Carolina | - |
dc.contributor.author | Martín, Nazario | - |
dc.contributor.author | Sánchez Costa, José | - |
dc.date.accessioned | 2021-07-16T09:04:36Z | - |
dc.date.available | 2021-07-16T09:04:36Z | - |
dc.date.issued | 2021-07-01 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/2445/179153 | - |
dc.description.abstract | Weak forces can play an essential role in chemical reactions. Controlling such subtle forces inreorganization processes by applying thermal or chemical stimuli represents a novel synthetic strategyand one of the main targets in supramolecular chemistry. Actually, to separate the differentsupramolecular contributions to the stability of the 3D assemblies is still a major challenge. Therefore,a clear differentiation of these contributions would help in understanding the intrinsic nature as well asthe chemical reactivity of supramolecular ensembles. In the present work, a controlled reorganization ofan hexakis[60]fullerene-based molecular compound purely governed by the weakest van der Waalsinteractions known,i.e.the dihydrogen interaction-usually called stickyfingers-is illustrated. This pre-reorganization of the hexakis[60]fullerene under mild conditions allows a further selective hydrogenationof the crystalline materialviahydrazine vapors exposure. This unique two-step transformation process ismonitored by single-crystal to single-crystal diffraction (SCSC) which allows the direct observation of themolecular movements in the lattice and the subsequent solid-gas hydrogenation reaction. | - |
dc.format.extent | 7 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1039/d1sc00981h | - |
dc.relation.ispartof | Chemical Science, 2021, vol. 12, p. 8682-8688 | - |
dc.relation.uri | https://doi.org/10.1039/d1sc00981h | - |
dc.rights | cc-by (c) Fernandez-Bartolomé, Estefania et al., 2021 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/es/ | * |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Ful·lerens | - |
dc.subject.classification | Ions | - |
dc.subject.classification | Química supramolecular | - |
dc.subject.classification | Molècules | - |
dc.subject.other | Fullerenes | - |
dc.subject.other | Ions | - |
dc.subject.other | Supramolecular chemistry | - |
dc.subject.other | Molecules | - |
dc.title | Playing with the weakest supramolecular interactions in a 3D crystalline hexakis[60]fullerene induces control over hydrogenation selectivity | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 713193 | - |
dc.date.updated | 2021-07-16T09:04:36Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 34257866 | - |
Appears in Collections: | Articles publicats en revistes (Institut de Nanociència i Nanotecnologia (IN2UB)) Articles publicats en revistes (Química Inorgànica i Orgànica) |
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File | Description | Size | Format | |
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713193.pdf | 1.33 MB | Adobe PDF | View/Open |
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