Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/179911
Full metadata record
DC FieldValueLanguage
dc.contributor.authorViayna Gaza, Antonio-
dc.contributor.authorGhashghaei, Ouldouz-
dc.contributor.authorVílchez Puyo, David-
dc.contributor.authorEstarellas, Carolina-
dc.contributor.authorLópez, Manuel-
dc.contributor.authorGómez Catalán, Jesús-
dc.contributor.authorLavilla Grífols, Rodolfo-
dc.contributor.authorDelgado, Jesús-
dc.contributor.authorLuque Garriga, F. Xavier-
dc.date.accessioned2021-09-10T09:41:09Z-
dc.date.available2023-07-18T05:10:14Z-
dc.date.issued2021-07-18-
dc.identifier.issn0016-2361-
dc.identifier.urihttp://hdl.handle.net/2445/179911-
dc.description.abstractThe increasing concerns about greenhouse gas emissions are encouraging the search for efficient combustion technologies for transportation. A valuable strategy consists of tailoring the properties of fuels through addition of additives that might increase the octane number subject to the classification, labeling and packaging regu- lation of fuel quality. In this context, we present an integrated approach involving a high-throughput screening that relies on selected physicochemical factors of aniline-like compounds, measurements of structural resem- blance and susceptibility to participate in chemical reactions with radical species, in conjunction with production viability as well as environmental and toxicological risks. This process led to a final set of representative com- pounds that were chosen to explore their behavior as anti-knock additives. The suitability of these compounds was determined through assays performed to determine the impact on fuel volatility and RON booster efficiency in conjunction with a critical assessment of their eco/toxicological risk estimated by means of a safety index. This holistic strategy led to the identification of N-methyl-p-anisidine, N',N'-diethyl-2-methyl-p-phenylenediamine and N-nitroso-diphenylamine as promising anti-knock additives. This approach is proposed as an alternative strategy to the unsupervised experimental screening of fuel additives.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherElsevier B.V.-
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1016/j.fuel.2021.121518-
dc.relation.ispartofFuel, 2021, vol. 305, p. 121518-
dc.relation.urihttps://doi.org/10.1016/j.fuel.2021.121518-
dc.rightscc-by... (c) Viayna Gaza, Antonio et al, 2021-
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.sourceArticles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)-
dc.subject.classificationGasolina-
dc.subject.classificationCombustibles-
dc.subject.classificationAnilina-
dc.subject.otherGasoline-
dc.subject.otherFuel-
dc.subject.otherAniline-
dc.titleHolistic approach to anti-knock agents: A high-throughput screening of aniline-like compounds-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.identifier.idgrec713501-
dc.date.updated2021-09-10T09:41:09Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)

Files in This Item:
File Description SizeFormat 
713501.pdf1.65 MBAdobe PDFView/Open


This item is licensed under a Creative Commons License Creative Commons