Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/22105
Title: Cationic distribution and intrinsic magnetic properties of Co-Ti doped M-type barium ferite
Author: Batlle Gelabert, Xavier
Obradors, Xavier
Rodríguez Carvajal, Juan
Pernet, Michel
Vallet Regí, María
Cabañas, María Victoria
Keywords: Ferrita
Propietats magnètiques
Cristal·lografia
Materials ferromagnètics
Cations
Química de l'estat sòlid
Ferrite
Magnetic properties
Crystallography
Ferromagnetic materials
Cations
Solid state chemistry
Issue Date: 1991
Publisher: American Institute of Physics
Abstract: The structural and magnetic properties of BaFe12−2xCoxTixO19 (0≤x≤1.0) M‐type barium ferrite have been investigated by means of neutron powder diffraction and high‐field magnetization measurements. The cationic distribution and magnetic moments of the five different metallic sublattices are determined and compared to the experimental saturation magnetization. It is found that about 50% of Co ions occupy tetrahedral sites, thus being ineffective in the reduction of the uniaxial magnetic anisotropy, while Ti ions prefer the 4fVI octahedral sites. All in all, a clear hierarchy of sublattice preferences is defined. Although the collinearity of the magnetic structure is progressively broken, mainly above x≊0.7, the overall behavior remains ferrimagnetic. The strong local spin canting is tentatively attributed to the localization of diamagnetic Ti ions in the 4fVI octahedral sites.
Note: Reproducció del document publicat a: http://dx.doi.org/10.1063/1.349526
It is part of: Journal of Applied Physics, 1991, vol. 70, núm. 3, p. 1614-1624
Related resource: https://doi.org/10.1063/1.349526
URI: http://hdl.handle.net/2445/22105
ISSN: 0021-8979
Appears in Collections:Articles publicats en revistes (Física de la Matèria Condensada)

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