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Title: Stereoselective Synthesis of (-)-Spicigerolide
Author: Georges, Yohan
Ariza Piquer, Xavier
García Gómez, Jordi
Keywords: Plantes
Botànica mèdica
Citotoxicitat per mediació cel·lular
Productes naturals
Síntesi orgànica
Medical botany
Cell-mediated cytotoxicity
Natural products
Organic synthesis
Issue Date: 2009
Publisher: American Chemical Society
Abstract: (-)-Spicigerolide was enantioselectively synthesized from a protected (S)-lactaldehyde. The synthesis of the polyacetylated framework relied on two Zn-mediated stereoselective additions of alkynes to aldehydes as well as a regiocontrolled [3,3]-sigmatropic rearrangement of an allylic acetate. The pyranone moiety was constructed via ring-closing metathesis.
Note: Versió postprint del document publicat a:
It is part of: Journal of Organic Chemistry, 2009, vol. 74, num. 5, p. 2008-2012
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ISSN: 0022-3263
Appears in Collections:Articles publicats en revistes (Química Inorgànica i Orgànica)

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