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http://hdl.handle.net/2445/101981
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DC Field | Value | Language |
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dc.contributor.author | Salomó i Prat, Ernest | - |
dc.contributor.author | Orgué Gassol, Sílvia | - |
dc.contributor.author | Riera i Escalé, Antoni | - |
dc.contributor.author | Verdaguer i Espaulella, Xavier | - |
dc.date.accessioned | 2016-09-20T15:49:47Z | - |
dc.date.available | 2016-09-20T15:49:47Z | - |
dc.date.issued | 2016-05-17 | - |
dc.identifier.issn | 0003-3022 | - |
dc.identifier.uri | http://hdl.handle.net/2445/101981 | - |
dc.description.abstract | The MaxPHOX-Ir catalyst system provided the highest selectivity ever reported for the redn. of cyclic enamides derived from α- and β-tetralones. This result indicates that iridium catalysts are also proficient in reducing alkenes bearing metal-coordinating groups. In the present system, selectivity was pressure-dependent: in most cases, a decrease in the H2 pressure to 3 bar resulted in an increase in enantioselectivity. Moreover, the process can be carried out in environmentally friendly solvents, such as methanol and Et acetate, with no loss of selectivity. | - |
dc.format.extent | 5 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley | - |
dc.relation.isformatof | Reproducció del document publicat a: http://dx.doi.org/10.1002/anie.201602219 | - |
dc.relation.ispartof | Angewandte Chemie International Edition, 2016, vol. 55, p. 7988-7992 | - |
dc.relation.uri | http://dx.doi.org/10.1002/anie.201602219 | - |
dc.rights | cc-by-nc (c) Salomó et al., 2016 | - |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/es | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Hidrogenació | - |
dc.subject.classification | Catàlisi asimètrica | - |
dc.subject.classification | Enantiòmers | - |
dc.subject.other | Hydrogenation | - |
dc.subject.other | Enantioselective catalysis | - |
dc.subject.other | Enantiomers | - |
dc.title | Highly Enantioselective Iridium-Catalyzed Hydrogenation of Cyclic Enamides | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 663024 | - |
dc.date.updated | 2016-09-20T15:49:52Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 27186653 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona)) |
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663024.pdf | 847.78 kB | Adobe PDF | View/Open |
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