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http://hdl.handle.net/2445/129477
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DC Field | Value | Language |
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dc.contributor.author | Kennington, Stuart C. D. | - |
dc.contributor.author | Ferré, Laura | - |
dc.contributor.author | Romo Fernández, Juan Manuel | - |
dc.contributor.author | Romea, Pedro | - |
dc.contributor.author | Urpí Tubella, Fèlix | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.date.accessioned | 2019-03-04T15:22:32Z | - |
dc.date.available | 2019-03-04T15:22:32Z | - |
dc.date.issued | 2017-06-15 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/2445/129477 | - |
dc.description.abstract | Direct nickel-catalyzed alkylation of chiral N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones using a commercially available nickel(II) complex, (Me3P)2NiCl2, has been developed for tropylium and trityl tetrafluoroborate salts. The reaction provides a single diastereomer of the corresponding adducts in good to high yields, which, in turn, can be easily converted into a wide array of enantiomerically pure compounds that are difficult to obtain by other asymmetric procedures. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Chemical Society | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.joc.7b00657 | - |
dc.relation.ispartof | Journal of Organic Chemistry, 2017, vol. 82, num. 12, p. 6426-6433 | - |
dc.relation.uri | https://doi.org/10.1021/acs.joc.7b00657 | - |
dc.rights | (c) American Chemical Society , 2017 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Catàlisi | - |
dc.subject.classification | Níquel | - |
dc.subject.classification | Quiralitat | - |
dc.subject.other | Catalysis | - |
dc.subject.other | Nickel | - |
dc.subject.other | Chirality | - |
dc.title | Diastereoselective and catalytic α-alkylation of chiral N-acyl thiazolidinethiones with stable carbocationic salts | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 672779 | - |
dc.date.updated | 2019-03-04T15:22:32Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
dc.identifier.pmid | 28525716 | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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672779.pdf | 521.7 kB | Adobe PDF | View/Open |
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