Please use this identifier to cite or link to this item:
http://hdl.handle.net/2445/138021
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DC Field | Value | Language |
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dc.contributor.author | Strekalova, Elena G. | - |
dc.contributor.author | Mazza, Marco G. | - |
dc.contributor.author | Stanley, H. Eugene (Harry Eugene), 1941- | - |
dc.contributor.author | Franzese, Giancarlo | - |
dc.date.accessioned | 2019-07-23T12:56:03Z | - |
dc.date.available | 2019-07-23T12:56:03Z | - |
dc.date.issued | 2011-04-07 | - |
dc.identifier.issn | 0031-9007 | - |
dc.identifier.uri | http://hdl.handle.net/2445/138021 | - |
dc.description.abstract | Using Monte Carlo simulations, we study a coarse-grained model of a water layer confined in a fixed disordered matrix of hydrophobic nanoparticles at different particle concentrations c . For c = 0 , we find a first-order liquid-liquid phase transition (LLPT) ending in one critical point at low pressure P . For c > 0 , our simulations are consistent with a LLPT line ending in two critical points at low and high P . For c = 25 % , at high P and low temperature, we find a dramatic decrease of compressibility, thermal expansion coefficient, and specific heat. Surprisingly, the effect is present also for c as low as 2.4%. We conclude that even a small presence of hydrophobic nanoparticles can drastically suppress thermodynamic fluctuations, making the detection of the LLPT more difficult. | - |
dc.format.extent | 4 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | American Physical Society | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.1103/PhysRevLett.106.145701 | - |
dc.relation.ispartof | Physical Review Letters, 2011, vol. 106, num. 14, p. 145701 | - |
dc.relation.uri | https://doi.org/10.1103/PhysRevLett.106.145701 | - |
dc.rights | (c) American Physical Society, 2011 | - |
dc.source | Articles publicats en revistes (Física de la Matèria Condensada) | - |
dc.subject.classification | Física de partícules | - |
dc.subject.classification | Nanopartícules | - |
dc.subject.other | Particle physics | - |
dc.subject.other | Nanoparticles | - |
dc.title | Large Decrease of Fluctuations for Supercooled Water in Hydrophobic Nanoconfinement | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 580873 | - |
dc.date.updated | 2019-07-23T12:56:03Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Física de la Matèria Condensada) |
Files in This Item:
File | Description | Size | Format | |
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580873.pdf | 2.28 MB | Adobe PDF | View/Open |
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