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http://hdl.handle.net/2445/143161
Title: | Ammonia-borane derived BN fragments trapped on bi- and trimetallic titanium(III) systems |
Author: | Del Horno, Estefanía Jover Modrego, Jesús Mena, Miguel Pérez-Redondo, Adrián Yélamos, Carlos |
Keywords: | Titani Radiocristal·lografia Teoria del funcional de densitat Titanium X-ray crystallography Density functionals |
Issue Date: | 2019 |
Publisher: | Wiley-VCH |
Abstract: | Titanium(III) complexes containing unprecedented (NH2BH2NHBH3) 2‒ and {N(BH3)3} 3‒ ligands have been isolated and their structures elucidated by a combination of experimental and theoretical methods. The treatment of the trimethyl derivative [TiCp*Me3] (Cp* = η5 -C5Me5) with NH3BH3 (3 equiv) at room temperature gives the paramagnetic dinuclear complex [{TiCp*(NH2BH3)}2(µ-NH2BH2NHBH3)], which at 80 ºC leads to the trinuclear hydride derivative [{TiCp*(µ-H)}3{µ3-N(BH3)3}]. The bonding modes of the anionic BN fragments in those complexes as well as the dimethylaminoborane group trapped on the analogous trinuclear [{TiCp*(µ-H)}3(µ3-H)(µ3-NMe2BH2)] have been studied by X |
Note: | Versió postprint del document publicat a: |
It is part of: | Chemistry-A European Journal, 2019, vol. 25, p. 7096-7100 |
URI: | http://hdl.handle.net/2445/143161 |
ISSN: | 0947-6539 |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
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