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Please use this identifier to cite or link to this item: http://hdl.handle.net/2445/159897
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dc.contributor.authorAmat Tusón, Mercedes-
dc.contributor.authorPérez Bosch, Maria-
dc.contributor.authorLlor Brunés, Núria-
dc.contributor.authorEscolano Mirón, Carmen-
dc.contributor.authorLuque Garriga, F. Xavier-
dc.contributor.authorMolins i Grau, Elies-
dc.contributor.authorBosch Cartes, Joan-
dc.date.accessioned2020-05-13T07:01:29Z-
dc.date.available2020-05-13T07:01:29Z-
dc.date.issued2004-11-06-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/2445/159897-
dc.description.abstractThe stereochemical outcome of the conjugate addition of a variety of stabilized nucleophiles (2indoleaceticenolatesandsulfur-stabilizedanions)tothephenylglycinol-derivedunsaturatedlactams trans-2, cis-2, and its 8-ethyl-substituted analogue 10 is studied. The factors governing the exo or endo facial stereoselectivity are discussed. This methodology provides short synthetic routes to either cis- ortrans-3,4-disubstituted enantiopure piperidines as well as efficient routes for the enantioselective construction of the tetracyclic ring system of uleine alkaloids, both in the normal and 20-epi series. The formal total synthesis of several alkaloids of this group is reported.-
dc.format.extent13 p.-
dc.format.mimetypeapplication/pdf-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/jo0487101-
dc.relation.ispartofJournal of Organic Chemistry, 2004, vol. 69, num. 25, p. 8681-8693-
dc.relation.urihttps://doi.org/10.1021/jo0487101-
dc.rights(c) American Chemical Society , 2004-
dc.sourceArticles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)-
dc.subject.classificationAlcaloides-
dc.subject.classificationLactames-
dc.subject.classificationSíntesi orgànica-
dc.subject.otherAlkaloids-
dc.subject.otherLactams-
dc.subject.otherOrganic synthesis-
dc.titleConjugate Addition to Phenylglycinol-Derived Unsaturated ä-Lactams. Enantioselective Synthesos of Uleine Alkaloids-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/acceptedVersion-
dc.identifier.idgrec568509-
dc.date.updated2020-05-13T07:01:29Z-
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess-
Appears in Collections:Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)

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