Please use this identifier to cite or link to this item:
https://hdl.handle.net/2445/161883
Title: | Field-Induced SMM and Visible/NIR-Luminescence Behaviour of Dinuclear LnIII Complexes with 2-Fluorobenzoate |
Author: | Casanovas Bayo, Berta Font Bardia, Ma. Mercedes Speed, S. El Fallah El Boufrahi, Mohamed Salah Vicente Castillo, Ramón |
Keywords: | Estructura cristal·lina (Sòlids) Magnetisme Layer structure (Solids) Magnetism |
Issue Date: | 11-May-2018 |
Publisher: | Wiley-VCH |
Abstract: | The reaction of Ln(NO3)2·6H2O salts (Ln = Nd, Eu, Gd, Tb, Dy, Er and Yb) with 2-fluorobenzoic acid (H-2-FBz) and 1,10-phenanthroline (phen) in ethanol/water mixture allows the isolation of dinuclear compounds of the formula [Ln2(2-FBz)4- (NO3)2(phen)2] {Ln = Nd (1), Eu (2), Gd (3), Tb (4), Dy (5), Er (6)} and [Yb2(2-FBz)6(phen)2] (7). The solid-state photoluminescence study of the complexes shows the 4f-4f lanthanide transitions in the visible range, in the cases of 2, 4 and 5, and in the NIR range for 1, 6 and 7. Magnetic studies reveal field-induced single-molecule-magnet (SMM) behaviour for compounds 1, 5, 6 and 7. |
Note: | Versió postprint del document publicat a: https://doi.org/10.1002/ejic.201800229 |
It is part of: | European Journal of Inorganic Chemistry, 2018, vol. , num. , p. 1928-1937 |
URI: | https://hdl.handle.net/2445/161883 |
Related resource: | https://doi.org/10.1002/ejic.201800229 |
ISSN: | 1434-1948 |
Appears in Collections: | Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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