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Title: Stereoselective alkylation of (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones catalyzed by (Me3P)2NiCl2
Author: Fernandez-Valparis, Javier
Romo Fernández, Juan Manuel
Romea, Pedro
Urpí Tubella, Fèlix
Kowalski, Hubert
Font Bardia, Ma. Mercedes
Keywords: Catàlisi asimètrica
Compostos de níquel
Enantioselective catalysis
Nickel compounds
Issue Date: 2-Jul-2015
Publisher: American Chemical Society
Abstract: The structurally simple (Me3P)2NiCl2 complex catalyzes SN1-type alkylations of chiral N-acyl thiazolidinethiones with diarylmethyl methyl ethers and other stable carbenium cations. The former can contain a variety of functional groups and heteroatoms at the α-position. The resultant adducts are isolated as single diastereomers in high yields and can be converted into enantiomerically pure derivatives in a straightforward manner.
Note: Versió postprint del document publicat a:
It is part of: Organic Letters, 2015, vol. 17, num. 14, p. 3540-3543
Related resource:
ISSN: 1523-7060
Appears in Collections:Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada)
Articles publicats en revistes (Química Inorgànica i Orgànica)

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