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http://hdl.handle.net/2445/173196| Title: | An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis |
| Author: | Amat Tusón, Mercedes Brunaccini, Elisa Checa Castaño, Begoña Pérez Bosch, Maria Llor Brunés, Núria Bosch Cartes, Joan |
| Keywords: | Lactames Alcaloides Compostos bioactius Química orgànica Lactams Alkaloids Bioactive compounds Organic chemistry |
| Issue Date: | 2009 |
| Publisher: | American Chemical Society |
| Abstract: | Ring-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R') also undergoes oxidation to the corresponding cyclohexenone C. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1021/ol901704f |
| It is part of: | Organic Letters, 2009, vol. 11, p. 4370-4373 |
| URI: | http://hdl.handle.net/2445/173196 |
| Related resource: | https://doi.org/10.1021/ol901704f |
| ISSN: | 1523-7060 |
| Appears in Collections: | Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia) Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) |
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| 571419.pdf | 141.41 kB | Adobe PDF | View/Open |
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